Electron-nuclear double resonance spectroscopy (and electron spin-echo envelope modulation spectroscopy) in bioinorganic chemistry.

Brian M Hoffman

Journal: Proceedings of the National Academy of Sciences of the United States of America 2003;100(7):3575-8

PMID: 12642664

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Abstract

This perspective discusses the ways that advanced paramagnetic resonance techniques, namely electron-nuclear double resonance (ENDOR) and electron spin-echo envelope modulation (ESEEM) spectroscopies, can help us understand how metal ions function in biological systems.

Address: Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208-3113, USA. [email protected]

DOI: 10.1073/pnas.0636464100

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MeSH Terms: Catalysis, Chemistry, Bioinorganic, Electron Spin Resonance Spectroscopy, Enzymes, Iron-Sulfur Proteins, Magnetic Resonance Spectroscopy, Metals, Proteins